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Duplex 2205 vs Super Duplex 2507 Round Bar: Which Grade Do You Need?

Duplex 2205 and super duplex 2507 share the same two-phase structure, but 2507 carries more chromium, nickel, molybdenum and nitrogen for tougher chloride and seawater service.

At a Glance

PropertyDuplex 2205Super Duplex 2507
UNS numberS31803 / S32205S32750
Chromium21.0–23.0%24.0–26.0%
Nickel4.5–6.5%6.0–8.0%
Molybdenum2.5–3.5%3.0–5.0%
Nitrogen0.08–0.20%0.24–0.32%
PREN (approx.)33–3640 or more
Min yield450 MPa550 MPa
Min tensile620 MPa795 MPa
Continuous service limitAbout 300°CAbout 250°C

What PREN tells you

The Pitting Resistance Equivalent Number (PREN) estimates resistance to pitting in chloride environments, calculated from chromium, molybdenum and nitrogen. Super duplex grades are generally defined as having a PREN of 40 or more. A higher PREN means more margin in warm or high-chloride service.

When Duplex 2205 is enough

2205 roughly doubles the yield strength of 316L and resists chloride stress-corrosion cracking far better. It suits heat exchangers, pressure vessels, pumps and general marine and chemical equipment with moderate chloride levels.

When to move to super duplex

Choose super duplex 2507 or S32760 for subsea equipment, seawater cooling systems, offshore oil and gas and high-chloride process lines, where 2205 would be marginal. The higher strength also allows lighter sections.

What about UNS S32760?

S32760 is another super duplex grade, with added tungsten and copper. Its corrosion performance is comparable to 2507, but the two UNS numbers are not interchangeable on certified work, so check which one your specification names.

Machining, welding and testing

Both grades need controlled heat input when welding to protect the austenite-ferrite balance, and super duplex is the more demanding. Avoid long exposure above the temperature limits shown, because of embrittlement. Projects commonly specify ferrite content and ASTM A923 testing to confirm freedom from harmful intermetallic phases.

Frequently Asked Questions

Is S31803 the same as S32205?
They are both 2205. S32205 is a narrower composition range within S31803, and many mills dual-certify bars to both.
Is super duplex worth the extra cost?
It is worth it when chloride levels or temperature put 2205 at risk, for example in seawater or subsea service. For moderate conditions, 2205 is the more economical choice.
Can duplex be used above 300°C?
Generally no. Prolonged exposure above about 300°C risks embrittlement in 2205, and the limit is lower for super duplex.